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where ftrans,sph is the coef cient of translational frictional force acting on a spherical macromolecule, rsph is the spherical macromolecular radius and is the viscosity of the aqueous buffer medium. Equation (7.2) is known as Stokes law. Under stick boundary conditions, the water molecules that comprise the immediate hydration layer interact so well with a given biological macromolecule that they move at the same pace as that macromolecule. Under slip boundary conditions, the water molecules that comprise the immediate hydration layer interact to a negligible extent and so have no forward velocity imparted from any given macromolecule (Figure 7.10). In the case of the rotational friction forces that oppose rotational motion, the coef cient of rotational friction force, frot,sph , acting on a spherical c# ean 13 reader .NET EAN-13 Barcode Reader for C#, VB.NET, ASP.NET Applications
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